Pyrolytic carbon (PyC) interphase is a vital constituent of Cf/SiC composite and a key factor influencing mechanical properties of materials. PyC interphases with different microstructures have different intrinsic properties and performances, which would be beneficial to adjusting the mechanical properties of Cf/SiC composites. To precisely control texture type of the PyC interphase, 9 groups of PyC interphases with low, medium, and high textures were designed and prepared in this study. Utilizing the DETCHEM software, the pyrolysis components and their contents of the precursor gas source (methane) under the 9 sets of different chemical vapor deposition (CVD) parameters were calculated, and the key parameter R' that determines the texture type of PyC interphase was identified. When R' of the pyrolysis component of methane is ≥ 22, it tends to deposite a low-texture PyC interphase; when R' ≤ 8.1, a high-texture PyC interphase is favored; when R' falls between 8.1 and 22, a medium-texture PyC interphase is formed. Furthermore, the CVD parameter range for different texture types of PyC interphases, PyC texture phase diagram are obtained, and growth models for different texture types of PyC interphases are constructed.
庞旭,洪旺,张中伟. 热解碳界面相的精细调控[J]. 航空制造技术, 2024, 67(22): 78-85.
PANG Xu, HONG Wang, ZHANG Zhongwei. Fine Control of Pyrolytic Carbon Interphase[J]. Aeronautical Manufacturing Technology, 2024, 67(22): 78-85.