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Effects of Doping Method and Sintering Additive Content on Microstructure and Thermo–Mechanical Properties of Si3N4 Ceramics |
HUANG Pengjin1, LI Yehua1, CHEN Xuanzhi1, LONG Guoqin1, LIU Youwu1, WU Shanghua1,2 |
1. School of Electromechanical Engineering, Guangdong University of Technology, Guangzhou 510006, China;
2. Guangdong Metal Ceramic 3D Technology Co., Ltd., Foshan 528225, China |
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Abstract Si3N4 ceramics with high thermal conductivity and high strength were fabricated through gas pressure sintering at 1 MPa N2 and 1850 ℃ , holding for 4 h in this study. Effects of doping methods (coating and traditional ballmilling) and sintering additive content on the phase composition, relative density, microstructure, mechanical property and thermal conductivity of the as-prepared Si3N4 ceramics were systematically studied. The results show that increasing the sintering additive content enhances the second-phase crystallinity, relative density, mechanical property, and thermal conductivity of the Si3N4 ceramics. Compared with the traditional ball-milling method introducing sintering additives, the coating method is more favorable to improving the dispersion uniformity of sintering additive, enabling Si3N4 ceramics to form a continuous network liquid phase with sintering additive mass fraction of merely 3%, thereby promoting the densification, improving microstructure uniformity, and ultimately enhancing the mechanical property and thermal conductivity of Si3N4 ceramics. The sample prepared using the coating method with sintering additive mass fraction of 5% achieved a thermal conductivity of 76.07 W·m–1·K–1, fracture toughness of 8.39 MPa·m1/2 and bending strength of 922.41 MPa, and showing a 13% increase in bending strength compared with the ball-milled sample.
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PACS: V26;TQ174 |
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